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At level 24, it took two shots to kill Rawr with buffs. He survived the first shot with 65 HP. So, current max damage vs. Rawr which has 45 levels, 900 HP, and 15 DT is 835. I probably should have waited one or two more PC levels.
At this point the only other one-shot challenge is:
Legendary Bloatfly (2,000 HP & 20 DT) in OWB
One-shot won't be possible:
X-42 Giant Robo-Scorpion: There are better ways to deal with this enemy, due to VATS bugs; enemy scales. Other than using Robotics Expert to deactivate, or Science skill on terminals, I have not found a better weapon than either of the LAERs.
Legendary Bloatfly (2,000 HP & 20 DT) in OWB
Normal Difficulty: One shot is easily achieved with overkill.
Very Hard: Not sure yet.
X-42 Giant Robo-Scorpion: Varies from 1500 HP & 15 DT to 3500 HP & 30 DT.
Normal: Was not possible at max scaling. Even when deactivated it required 3 shots.
Very Hard: No way, not unless mods or additonal buffs like Lily could be added.
I'd have to dig through my screencaptures, but I think my highest Paciencia hit to date was 2,800+ on Normal. However, this character has quite a ways to go before that sort of damage.
add- Yup, I only have 385 HP currently and don't usually wear armor. I'd have to buff with the 80% DR (functional cap).
This character hasn't done challenges or taken species perks either, so if she can't do it, I may edit her once at level 50 and add Entomologist or whatever might help, then import a new copy of the monsters to test.
https://steamcommunity.com/sharedfiles/filedetails/?id=2457214995
https://steamcommunity.com/sharedfiles/filedetails/?id=2457162689