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The ammo crafting is useful in general, bottlecap mines are nice but satchel charges are much better and easier to make.
If you have the mad bomber perk then MFC grenades are cheap and an interesting option for explosive characters, while MFC clusters are crazy strong and not difficult to make.
Nuka grenades are surprisingly spammable with the nuka chemist perk and hilariously powerful.
Many of the handloader exclusive ammo types.
Hydra.
Desert salad.
Healing poultice.
Snakebite torniquet.
If you crush/talk Ulysses down, he also teaches you bitter drink.