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http://fallout.gamepedia.com/Detonator_(Fallout:_New_Vegas)#Locations
but theres enough C4 in that vault just lying around isn't there...
from the wiki:
You can find four packs of C-4 within the vault:
Between filing cabinets in the clinic, behind the front desk.
Located between the two vending machines in the cafeteria.
Outside the underground entrance to the overseer's office elevator near the doorway with the firehose box. When facing the firehose box turn left towards the junk pile, the C4 is on the left side of the junk pile.
Located under a couch in the Blue Sector living quarters (not the first floor). Go to the second room on the right, then to the couch left of the door. The C-4 should be next to the right front leg of the couch (looking at it; left leg sitting in it). However, it may be completely invisible or disappear when the player approaches it. It can easily be found by crouching and inspecting the floor close to the leg.
http://fallout.wikia.com/wiki/C-4_plastic_explosive
I would have half of the Achievement's by now, sighs.
If you use a console command, or even just accidentally hit ~ at any time, achievements disable until you save the game, quit to desktop, then reload it.
You don't need to start a new game.