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If you use the item list module you could just buy the steel from that.
The other way to get your hand on valyrian steel is to captured lords and execute them, be aware that only a few specific lords have valyrian steel weapons.
Plus, if you want to get your hands on Ice, the sword of the Starks, you have to conquer Winterfell then look for the Weirwood tree, there will be a chest underneath the tree with Ice.
This article might help: https://aworldoficeandfire.co.uk/wiki/index.php/Valyrian_Weapons