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When the Molotov is thrown, hit VATS and shoot the Molotov in VATS with a VATS-optimised weapon.
Watch out for the red grenade icon and sprint out of there - more or less any direction is better than standing still.
Get high ballistic damage resistance. Molotovs count as ballistic damage, stupidly.
If all else fails as the Molotov is about to hit you go into Pipboy and take Buffout, Med-X and Psycho and any chems that give instant HP or instant END.
But mainly, on Survival, you need kill them before they get a chance to fight back.
Other than this you can try what other have mentioned to make it less likely for you to take damage.
If you can find the right legendary effect on an armor part that reduces damage from humans that would help as well.