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Organic components (little claw thingie icon) boost the item XP gain. ×3 is the best you can get, although it's hard to reach that high with early components.
Synthetic ones "screw icon) add tons of XP, but are rare, expensive, and decrease the XP bonus, so you need to apply them by large amounts.
Easiest way to upgrade is to sell every synthetic one but the expensive ones, buy more of the same ones you kept, then use organics to boost multiplier, then add in the synthetic ones by bulk (at least 10, or the amount for max). There are guides where you can check how much XP an item needs and what item is used to change it to something else. This one is probably the easiest to use: http://guides.gamercorner.net/ffxiii/
It's not a bad idea to boost accessories first, since they seem to not affect the target times, and you can get some really neat stuff quite early on. Weapons on the other hand decrease the times you need to get 5-star rating, which is a must if you ever want to 100% the game, or just want the good loot.
For weapons my advice is to pick one or two characters and only boost their weapon. Vanille is usually a good choice, since the Belladonna Wand has a very useful ability, and it's easy to boost it. With a decent level Belladonna/Malboro wand you can take on the Sazh/Vanille segments a lot easier.
2. Lightning: Axis Blade (get this to Tier 2 (upgrade to Star then Catalyst) as soon as you can)
Hope: Hawkeye
Fang: Taming Pole (go for this one as soon as you can, since Fang is the best COM)
Sazh: depends, i'd go with Vega 42
Snow: Paladin
Vanille: Belladonna Wand
3. You can start upgrading in Chp 9, since it's the first time you can farm easy Incentive Chips to sell and get components. The recommended time for upgrading is Chp 11 since by that time you have gil and can buy good components, but the best time is after doing Mission 7 (Bituitus), since you unlock the shop which features the best synthetic components in the game.
Bonus: Upgrade Whistlewind Scarf and use a Catalyst to make Aurora Scarf which gives you full ATB at the start of the Battle (very useful item until Postgame).
Upgrade Tetradic Tiara to Star Level and dismantle it to get Sprint Shoes (Auto-Haste)
Upgrade Collectors Catalog to Star and use a Catalyst to get Connosieur Catalog (increases rare drop chance).
http://concubidated.com/ffxiii/ use this link to calculate necessary number of Synthetic Components for your Weapons
I totally didnt knew that lols.
Ok im buying new crap weapons so i can get 5 stars from now on :P.
Huh? It's very possible to complete the game fairly easily without upgrading.
When a weapon levels up to tier 2 (around lvl 30-40) then it becomes a new weapon once you upgrade it with a special element, and then you can upgrade it to tier 3 (Thats the stuff that has +600STR/Mag etc)
Each character has a high str,low mag and vice versa. If in doubt, then just upgrade a medium str/mag weapon since untimatly, you will be using the same weapon (although upgraded) throughout the game. Just upgrade it whenever you want, no need to hold back (Just buy 36 sturdy bones to get 3x upgrade multiplayer anytime you want)