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On the surface as raw material it's silvery/white easily confused with gold.
Just keep trying different planets until you find one rich in Aluminium. The scan result is the grey treasure chest icon for the green crystals which are best.
Sorry to tell you but yesterday i found a planet with huge pillars of Aluminium almost everywhere you land... :)
It's always a good idea to check out all the planets in a system to get an idea of where the resources are. You'll usually find everything except the really rare stuff.
http://steamcommunity.com/sharedfiles/filedetails/?id=746519741
Bolshevikii // Jomo Kenyatta - aluminum crystals
Trotsky Landing // Julius Martov - aluminum on surface