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As for materials, if you have extra slots might as well grab any o2 and na that you got, also h2... other than that, I couldn't think of too much that you'd get during the expedition that you couldn't also easily get on a normal play.
See: https://youtu.be/bLdBdbRiZUc?t=395
Stasis Devices, Fusion Igniters, Cryogenic Chambers, Cryo Pumps, Quantum Processors, Circuit Boards, Portable Reactors, Liquid Explosives, Unstable Gel, Fusion Accelerant, and Organic Catalysts are all strictly to be sold to make Units, or used to craft things which you sell to make Units.
Stasis Devices and Fusion Igniters are the end-products, selling for 15 million units each. Setting up farms and automated mines to facilitate crafting stacks of these is extremely lucrative, and can easily net you over 1 billion units from 24 hours of production.
The biggest bottleneck is the plant products required. You can either make a massive, massive farm, or a few automated mines and then use refiner recipes to convert metals into plants.
There are also some alloys in the crafting path which have other uses. Dirty Bronze, Aronium, and Herox make Silver which is a mainstay for Freighter components, Grantine, Magno-Gold, and Lemium makes Gold which has some important crafting uses.
The Photonix Core was also available on my PC preorder.
Once you have the Photonix Core can it simply be crafted over and over like other ship drives?