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You cannot buy oxygen anymore unless you are playing with the lowest difficulty setting for resource availability. Removing certain materials that used to be commonly available is one of the changes made when they added custom difficulty options.
You will also note that batteries and life gel are also not for sale anywhere either.
Edit: I should mention I only said "unless you are playing with the lowest difficulty setting" because I still see people mention oxygen being available at the trade terminals (example just a few posts up), so I assume it must be available on the lowest setting.
I haven't actually played with that setting turned down, though, so I wanted to clarify that this is just an assumption. What I do know for sure is that it is NOT for sale at higher difficulties.