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Carbon is not good as most of your ship. Since shield penetration means a small amount of damage will go through shields, which will be enough to shred a weak material like Carbon. It takes a fair number of shield penetrating hits to go through Steel though.
Xenosteel is also not the ultimate hull block either. It has the best mass:hp ratio, but is functionally weaker than combat steel in raw hp. It adds significantly more hp to your shield than other armor blocks though.
Realistically, only the parts of your ship that are going to take heavy fire need to be Combat Steel. Hardened Steel and even just Steel are fine for places that aren't likely to or won't be hit. Even carbon is fine for small decorative details and internal work.
Xenosteel have the best hp:mass ratio and each block increases your shield capacity by a fair amount. They're susceptible to lasers, but have added resistance against Railguns, Plasma and Legacy Disruptors, which all do bonus damage against metal hull blocks.