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the answer is literally
3 comments down, its sold by the travelling merchant
In the meantime, Recipe Browser can be used to view all the crafting recipes and enemy drops. For NPC-sold items, I made a pinned discussion thread on this workshop page you can look at (Go to the Discussions tab at the top of this page).
Ace of Hearts is sometimes sold by the Travelling Merchant.
Depending on how strong you are, you may be missing the mini-hearts because groups of enemies are being killed within 5 seconds of eachother, and/or enemies are killed before you get a crit.