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If you are using an ethernet cable; Is it possible you need to switch off the wifi adapter in firmware (bios/uefi) settings?
As an alternative if you are not using wifi physicaly remove the wifi adapter.
I may try physically removing the adapter. I don't know if the adapter's even working or not, it could be DOA as I've seen no sign of life from it whatsoever. However at this point I am beginning to believe that Steam OS just doesn't natively support the Ethernet port and I don't have the drivers for my PCIE wireless unit, and I don't have the user account priveleges to manually change files etc, so I'm just trying to install Windows instead and in the future I may try Steam OS again after I've made sure all my parts are functioning as they should be.
To be honest going by this Ubuntu (another Debian based OS) thread your wifi adapter does not play well with linux. ref: http://ubuntuforums.org/showthread.php?t=1988161 and a quick web search confirms your Intel I218-V Ethernet Port has issues with Debian due to driver issues. You could try and get the driver or confirm your internet connection works or not by following what lev258 suggests in using a non beta installer live session from a well established distribution.
ref: http://unix.stackexchange.com/questions/107226/no-ethernet-card-while-installing-debian-stable and http://forums.debian.net/viewtopic.php?f=7&t=112327
You could also post your issue on github where a Valve dev could see the need to do something about getting this hardware supported in SteamOS but the truth is if your machine is not one of the three hundred prototypes or a Gigabyte Brix it is not officially supported as well as Debian struggling with it any hows.
https://github.com/ValveSoftware/SteamOS
The easy option is just use windows until SteamOS is a bit more functional, capable and user friendly with better hardware support.
Referring to your mobo vendors's website[www.asus.com] the user manual[dlcdnet.asus.com] indicates the supplied DVD has windows drivers only.
Intel do provide linux drivers for their hardware and for your ethernet you want the e1000e driver. You can download the ethernet linux driver here[downloadcenter.intel.com]
For wifi the linux driver you want can be found here[support.asus.com]
Reading the links in my last post will help getting gist of what you could try to get things working the trouble is steamos needs that internet connection to install awak.