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Edit, per PnP Paladins have it innately (but again not in game)
Detect Evil (Sp)
At will, a paladin can use detect evil, as the spell. A paladin can, as a move action, concentrate on a single item or individual within 60 feet and determine if it is evil, learning the strength of its aura as if having studied it for 3 rounds. While focusing on one individual or object, the paladin does not detect evil in any other object or individual within range.
So then it should be able to be used to see "can I cast this spell on this target? ok it let me do it then it is evil".
So just cast Protection from Evil all the time just to be sure.
Also, high level version (Holy Aura/Shield of Law/Unholy Aura) also gives you spell resistance, immunity to mind affecting spells & blind.
Sadly again, the way protection from evil is implemented is only the basic stuff. It's missing quite a bit.
https://www.d20pfsrd.com/magic/all-spells/p/protection-from-evil/