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http://dota2.gamepedia.com/Demon_Eater
you see that gem on demon eater set called "inscribed three shadowraze combo". IT'S ONLY FOR THE DEMON EATER SET. if you could use it for the "arms of desolation" then you'd see that same gem on it's page aswell.
The wiki doesn't list every usable gem for every item. That'd be dumb.
Inscribed Gems are just for tracking stats. They can be removed and put into other things. For example, Rune of the Duelist Indomitable for the LC arcana can be slotted into any other item - it loses the custom visual effects, but it still tracks duel victories.