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He will drop higher level ones in TVHM, but it is only in UVHM that he will drop gear that is your level.
Elemental versions are a lot less likely to spawn - non elemental has something like a 4x greater chance than the elemental ones. They can spawn in normal, but they are not common.
Farming Doc Mercy in normal is not really worthwhile, because you level up and he doesn't, simple as that.