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The extra singularity comes into play when you're on co-op to set someone else up for a guaranteed carpet bomb on the entire mob (or set it up for yourself if you want). It also might help in more situational circumstances, such as during a Master Gee raid when I messed up my converge and Gee didn't go near the acid pool. Fortunately, I had the grenade and the singularity from that helped (but that goes for any singularity grenade really). The Rubi is also a gun you should definitely consider adding to your arsenal (preferably one that's element is slag).
This pretty much.
The evolution of grenade application as you approach the end-game content:
->destruction->dealing damage->slagging->healing->healing by dealing damage->repositioning of enemies
Quasar is the strongest-pull singularity out there, making it number one tool for repositioning your enemies. It's on top of the grenade evolution ladder. Best quasars come with a Longbow prefix and a 0.0 trigger period. In case you have one that features both of the mentioned attributes, it's going to serve you well regardless of the level gap between you and your precious grenade (pull effect is not influenced by the item level).
otherwise I would spend all my time using a quasar to set up sweet b0re kills
But yeah, Chain Lighting is a mandatory gear for an assassin.