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Blue-purple mods can be farmed at vending machines in sanctuary. There're 3 zeds dispensers and each may have good mod as item of the day. Just bring cash and restart in Sanctuary till you get one.
If you have the Mercenary Day DLC, the chest after the boss always contains some of everything, including relics and class mods, but getting blue or purple versions, especially in Normal Mode or TVHM, is a matter of luck.
BNK3R is another possibility. He seems to usually drop a few relics and class mods, and blue and purple ones don't seem that unusual, although, again, that may depend on the mode/level. Similarly, you could try the Warrior if you've gotten that far, since he drops a lot of miscellaneous stuff.
However...it is starting in level 50 and up where you get the best and most plentiful relics.