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On your second (and third) playthrus, enemies will scale to your level. Bosses/unique enemies will ALWAYS spawn at or around your level.
Don't get bogged down trying to farm items on your first playthru:
1)The difficulty is low and doesn't warrant that type of grinding.
2)You will level up so quickly that these items will become useless very quickly.
I'd suggest not farming until 72, or if you get to a point where your current guns are too weak and preventing you from completing missions because of that -which shouldn't happen until UVHM-.
On that note, I recommend you to get Good/Bad Touch from Moxxi - it will be closer to your level, and not too hard to receive. Not as good as Hellfire - but pretty solid elemental SMGs.
Also, there are half a dozen siren-specific ways of regenerating health, so Moxxi weapons are a bit overkill on the healing department if you're using a siren.
So yeah, while both weapons are about as good stat-wise, I'd say that for the particular case of a siren, a Hellfire will do way better than a Good Touch.
I don't know about perfect Good Touch; can't be bothered to keep reloading the game until I get a specific weapon, so i usually go with whatever random reward I get.
Here are my Hellfire and my Good Touch together:
http://steamcommunity.com/sharedfiles/filedetails/?id=455669790
Well, the perfect Good Touch would be as many Maliwan parts as possible - Barrel, Stock, Grip. The Sight doesn't have any modifier, except for zoom, so anything you'd prefer there.
As it turns out, the Good Touch always has a Maliwan Barrel (it's a Good Touch specific version of the Maliwan Barrel technically), so you only need to look for a Maliwan Grip and Stock.
Having a Maliwan Grip (looks like a curved foregrip, leading from the Stock to the underside of the Barrel) adds both extra elemental effect chance, aswell as a fairly high reload speed bonus. Worth saying that with guns, matching Grips to the Manufacturer (i.e. Jakobs Grip for Jakobs etc) gives that reload speed bonus and extra magazine size)
I used the Weapon Parts guide that was posted in the guides section for Borderlands 2, which has fully detailed pictures of these parts and what they look like.
Link - http://steamcommunity.com/sharedfiles/filedetails/?id=447124636
However, back on topic, not worth farming the Legendaries, such as the Hellfire, until you're in UVHM (L50+), ideally in the end game state at L72 and the OP levels.