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In TVHM it is the same UNTIL you beat the last boss again. From that point forward enemies scale with your level.
But aside from quest-weapons and the skyrocket - items do NOT change after they dropped.
To get your current level infinity pistol, you need to start TVHM, the next harder gameplay. Since its a new game, everything is reset and Doc and the infinity pistol will again be near the scaled level when you first enter that area. So NOW in your 2nd playthrough with TVHM and your level 30ish you can get a level 30ish infinity pistol when you farm it from Doc. I think mine was level 32 when i grabbed it.
Like normal mode, the pistol will stay at the scaled level when you first entered the area, so it will be useful to a point until you get to levels 40+, then you probably have better weapons (im still using mine as my main weapon at level 37ish). In order to get it higher, again you'll have to beat the game, and restart in the 3rd playthrough UVHM when again you can get it scaled to your level when you first enter the area on UVHM.
When you've reached level 30, you'd return to the boss you killed at level 5 who dropped your level 5 Infinity [Doc Mercy] to kill him again at Level 30 for your desired Level 30 Infinity. As soon as you've got the new one, you'd drop or sell the old one. Happy Gaming