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so gasses in liquid pipes they break
liquids in gaspipes they break
solid in both they will break
Liquid hydrogen is also very inconvinient to work with in general, without exploit mentioned above, because of very narrow temperature range in which it stays liquid.
https://oxygennotincluded.gamepedia.com/Super_Coolant
And since you need something to cycle through pipes without freezing, you essentially have to use it to get liquid hydrogen.
The thing is also far superior to liquid hydrogen an any possible way as coolant, the only problem arises when you want to go above boiling temp, but the hydrogen will not help you here too, you will need to find something that stays liquid reliably within temperature range you want to use (possibly hydrogen in gaseous state, if you do not need very fast heat transfer).
Also be mindfull about what you are building pipes/walls from, some materials like granite may melt and cause issues.
Magma volcano... just block it with insulated tiles out of obsidian for now, you will figure out how to use it WAY later.
For metals though, they have relatively low SHC and high conductivity, they generally cool down to relatively safe temperatures fast.