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Plasma and freezing are all right, but their damage is resolved per attack and not per bullet/pellet, so aren't all that great for shotguns.
Wounding would be your best option, especially for an automatic weapon or shotgun. Each bullet/pellet applies the effect, and the effect actually stacks (and despite being bleed damage, it hurts all enemies including robots). Furious isn't bad either, but that one can't be gotten on a randomly generated ranged weapon. It can be gotten on 2 handmade rifles from Nuka World, however.
The Wounding automatic pipe rifle is really good early in the game and it's my primary weapon.
But I also like the full modded radium rifle for all humans like raiders, with a Legendary effect too.
The Splatter Cannon, from the merchant in the Nuka World Market, is it's twin. But very costly.
Maybe two heads really are better than one! For a radiation-mutated cow at any rate.
But, as others have said,, you cannot go wrong with Wounding.
-- If playing on lower difficulty, almost nothing about the build or the weapon matters.
-- Playing on VH or Survival - you'll want to not have automatic weapons at all, because receivers nerf the damage and thus risk you to be exposed to prolonged fights (as automatic weapons imply) + waste ammo.
But. If you really want to make use of automatic weapons, your bet isn't the damage but some sort of effect that those weapons have, ideally a crowd-control one. For instance, 50% more limb damage or kneekapper effect go well with these weapons. Your bet is to immobilize the enemy and then use explosives or maybe heavy weaponry to deal with them while they struggle to reposition or get close.
But. If you really want to still do damage, prepared to waste a lot of ammo, you want explosive effect + radium rifle + fully upgraded demo expert + nuclear physicist. That will do a lot of damage at the expense of the need to be some distance away (so no using it in some vault or indoors). It also uses .45 caliber that's common which means ammo waste isn't that bad. This option is also good because you don't have to try getting it from rng loot - just buy Kiloton rifle from Brother Kane in the Nucleus, Far Harbor DLC.