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Grape Mentats just boost your CHA as far as I know.
An easy test is to do the same test on the other vendors there at Far Harbor.
In fact if the caps amount isn't moving at all, zero, you don't need Grape Mentats to test it, you can test it with a beer (+1 CHA).
*e;g Arturo in DC
Like I said, compare to other Far Harbor traders.
There might be a bug, it's possible.