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Your screenshots are stored where you tell Steam to store them. Click the top of your library window's "STEAM" button. Find SETTINGS and click it, it will bring up a popup window.
Find IN-GAME. Click that, it will show you the Steam Overlay page. The screenshot shortcut (normally f12) and right below that is a bar that says SCREENSHOT FOLDER. You can CHOOSE where that is! (also I highly recommend if you have enough hard drive space on that folder's location - click the SAVE AN UNCOMPRESSED COPY because the ingame or normal screenshot quality on steam is absolute junk)
To more easily share your screenshots you're not done yet though - in the settings popup window, click on CLOUD. That will give you the "open the screenshot uploader after closing a game" option! Click that, there you go! Whenever you use the overlay now, it will save a nice version in your choice of locations, tell you that it took a screenshot, and bring those up when you're done playing so you can upload them to steam.
If you haven't set a default location or don't know where to look otherwise, most steam games will also have their screenshots stored outside of that folder, in the game's userdata folder.
That's (your drive letter where steam is) steam / userdata / (a bunch of numbers - that's your account) / a bunch of folders! Those are the Steam game IDs for the games you have installed or played. The game information is in each, but the one you want to find is folder 760.
That has 'remote' and those are the folders with screenshots and some other info for each of your games. Fallout 4 is 377160. You'll find your screenshots and their thumbnails there.