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You must collect it from time to time, so it can be generated again.
edit: unless I personally place more in the storage myself.
I believe the maximum amount of "storage space" for purified water depends on how much water the settlement is producing.
In my current main save file, I have a settlement with about a dozen large water purifiers set up around it. It appears to store up to about 250 or so bottles of purified water at a time.
Sounds about right. I have many of my settlements set up with excessive water production in mind, and I routinely "make the rounds" passing through every settlement to collect the extra water and crops they generate.
Funnily enough, I eventually got to the point where I had so many settlements, that the time it takes to complete one full "round" through all of them is enough that the first settlement will have already generated a new stash of excess water. I could theoretically just keep travelling through all of the settlements in an infinite cycle, collecting infinite water. :P
But really, once you get past a certain point in the game, money becomes more or less meaningless because you won't really need to buy new weapons or armor anymore.
I can make around 800 bottles every few in game days at taffington boathouse
http://steamcommunity.com/sharedfiles/filedetails/?id=678812126
The trick is use the resources you can find from the surrounding settlements to start up the purifier production, then as the water accumulates, use those first sets of bottles of water to buy the materials needed to expand the purifiers, and it will get easier and easier.
yea and this is my power grid for it
http://steamcommunity.com/sharedfiles/filedetails/?id=678811408
I can't use them cause they require the science perk, I have to keep intel low for idiot savant perk to work faster for leveling.