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On PC, it is the Alt key. Pressing it causes a weapon bash (or power attack, if using a melee weapon), holding it down until you hear the click prepares a grenade (provided you have a grenade, mine, or molotov selected in your Pipboy), which will be thrown once you release the key. With the right perk, if you don't have an explosive of some kind selected and are in power armor, it will instead eject a fusion core at your feet that acts like a grenade.
The Left Alt key for pc. But the grenades need to be selected in your inventory or quick keyed ( Q ) to equip them.
That explains things.
You have the Nuclear Physicist perk at rank 3.
Because that enables you do eject your power armor's fusion core as a makeshift mini-nuke by pressing a button.
The kicker: Bethesda use the same hard-coded button for grenade throwing by holding it.
On PC this is extra fun when you want to Alt-Tab to your Windows desktop.
Update: I have recently moved onto Win 11, and several 'bugs' have been noted. I dont know if 11 is the problem, but after I had read the posts (thank you all) I put game on and saw that the Frags had been removed to make way for the FC throw. I dont think this was win 11, I think the game in Win 11, possibly. I reinstated the frags and it works again.
I suppose that I would have to start again, or at best go back until I no longer have nuc level 3??? Whatever it was, I didnt touch nuffin guv!
https://fallout.fandom.com/wiki/Nuclear_Physicist#Ranks
So something like:
Nuclear Physicist - No Fusion Core Ejection