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I've noticed Arturo begins to sell 20-30 bullets of .50 caliber after the quest "Unlikely Valentine" is completed. I'll have to look into it, but my vast amounts of purified water back at the house sure do make for some sweet caps.
With the finder perk tht gets you extra ammo found. Then look for those Ammo Boxes. The above mentiond Traveling merchants and shop vendors are also good places . More so after you Perk mercantile skills.
You should be able to one shot even a friggen death claw or some freaking raider in power-armor. That has gone unrealistically stupid.
I'm okay with unrealistic .50cal power for as long as Sniping is stupidly easy. If you want one-shot everything .50cal sniper shots, I want differential calculus to be a mandatory part of getting a shot on target at ranges > 100m
This is by design. You are supposed to use smaller rounds in earlier levels and advance up to heavier rounds in later ones.
With that said, Scrounger perk will impact the frequency of finding .50 cal ammo in boxes. The description of this perk is a bit deceiving. You don't find more of the same ammo but rather you find an additional type of ammo in the same box. For example, my experience is that instead of finding 25 rounds of .38 instead of 15 rounds, you find 15 rounds of .38 and 10 rounds of .50 cal or some other type of ammo.
I believe they started appearing when I was around level 16-17.