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Some of the dlc add chems, clothes and armor that will add some to Charisma if used.
Edit.
yes there is also that mentioned in post 8. I forgot about those since it is so rare I actually can save all the settlers.
Rogue Robot Missions.
If you do the radient Automatron missons given by Izabelle Cruz then you can ask any saved settlers to join one of your settlements.
Any settlement even if you have reached your Cha + Cha gear + Cha Chems +10 max.
Springcleaning : Lets you delete/scrap lots of junk
another one I forget the name of, but it keeps Raiders from (mostly) spawning inside settlement borders. AFAIK, none of them affect number of settlers you can have, that number is related to your Charisma
I did max out CHR, have lots of CHR boosting gear, and make liberal use of Grape Mentats
Sorry it is max 48 charisma aka 58 settlers without rogue robot