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Doing the Brotherhood missions means you can get some PA pieces as rewards and they have certain upgrades on
eg A chest section with Core Assembly on it.
But only for T-60 pieces.
You will not get a full set fully upgraded (or even half upgraded) though with just the pieces you find/ get as rewards and not all the choices on the Misc upgrades which you will only get for the T-60 pieces from the Brotherhood.
Teagan or The Atom Cats may sell PA upgrade schematics.. Dont Know. As I always run with Science and Armourer eventually, especially when running a build that use PA. So never noticed as I didn't need them.
However, if you want that fully kitted out Enclave armor (X-01), then you'll need to level up Armor and Science. If you're doing a Cha build you'll probably want Science for the settlement building too. I haven't really used PA much myself (running an unarmed build, so PA is the enemy), other than exploring high RAD areas.
I've seen her sell mods for T-45, T-51, and T-60 sets, but not for X-01 or raider power armour. Specifically, Hydraulic Bracers, Overdrive Servos, and Titanium Plating for T45; Calibrated Shocks,Core Assembly, Emergency Protocols, Lead Plating, Optimized Servos, abdVATS Matrix Overlay for T-51; and Explosive Vent, Kinetic Dynamo, Medic Pump, Photovoltaic Coating, Prism Shielding, Rad Scrubbers, Reactive Plates, and Sensor Array for T-60.
Yep, I thought she may but couldn't be positive as I said.
And yes they are one use Mods for PA they dont give you the ability to build more of the same.
Brain Fart momment in the way i named them.