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http://fallout.wikia.com/wiki/Liberty_Prime
I suspect that since it really only becomes a 'character' in the game when you run BOS it's not meant to be a bullet sponge for YOUR weapons.
Once that is done, complete the game as the Minutemen, and "With our Powers Combined" should trigger, destory the Prydwyn, this however will not kill LIberty Prime who should be wandering around the Airport. Prime is now Non-Essential, and killable. He has over a Million Hitpoints and inflicts 10,000 Damage with a high-accuracy Laser. Have fun.
Like Swan, he Regenerates immediately if left idle, so sneak-attack spam doesn't really work. The moment you register as Hidden, his HP is restored.
Mininukes are not particularly effecitve, your best bet is to strafe with an obscene high DPS weapon, like a Two-Shot automatic plasma rifle. It will take around 800 rounds to kill him.