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Of course, you can't junk pipboy game tapes and other such tapes, but you can dispose of them.
The world is a dump, even the clothes you find can be scrapped and turned into floor mats and chairs. A definitive list would be long.
Abraxo Cleaner to make Mentats
Antifreeze Bottle to make Berry mentats. (Pretty uncommon item so if you want to make this, keep it out of the workshop. Breaks down into acid and plastic so most likely gets scrapped as soon as you build something that needs either of those.)
Halluciegen gas Container, only 8? can be found at Hallucigen Inc, and dont respawn I think. Not sure on that. Stored in junk, breaks down into steel and 1 is needed for a misc quest in goodneighbour. Can also be used to build a frenzy gas grenade, so yeah, great thinking from who-ever thought that up.
Buffout, not that rare but only chem that cant be made, and imo more usefull to be turned into psychobuff and bufftats.
baseball to make baseball grenades
bloatfly gland(1) for a misc quest in diamond city
syringer ammo needs some specific junk items, though havent used it myself so you'll ahve to look those up yourself.
but if you scrap it for parts its gone and you aint getting it back
settlements- cloth, concrete, steel, wood, food to plant.
Biometric scanner x 1 and military grade circuit board x 1 for the molecular relay.
High-power magnet x 1 for liberty prime quest.