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I would advise you to ignore the metal-rich rings. Cores from rocky rings are worth a lot more, and platinum in a metallic ring is a lot easier to get.
Laser mining platinum from a hot spot in a pristine metallic ring is about as lucrative as it gets if you are just after credits. However the combination is just too hard to find to be useful for power-play merit purposes. If you are able to fine any metallic ring (even without hot spots) in your system where the demand is, I recommend a hybrid approach instead. Start with your core-mining loadout and add to that a mining laser and a sub-surface displacement missile launcher (not to be confused with sub-surface extraction missile which was used to get people out of Thargoid titans). When you get to the metallic ring, use your pulse-wave analyzer to look for bright-lit rocks and send a prospector in them. Even if a core isn't present, there is a very good chance of surface or sub-surface deposits you can blow for platinum, painite, and osmium using your abrasion blaster or displacement missiles (respectively). The mining laser will do the trick if the rock happens to have a good ratio of platinum or osmium. Then if a core is present, do what you do as a core miner with the seismic charges and abrasion blaster. Don't forget your limpets. Filling up on valuable stuff to sell should be relatively quick this way.
In the case of gold and silver, which can come from either mining or extraction stations, how you get it does count. Mining minerals from a ring or belt means you sell in-system or it doesn't count regardless of what the mineral is. Gold and silver that came off of station market will count as trading merits as long as the profit is good enough. But it has to be sourced from an actual station market, and not a ring, belt, or fleet carrier.
If you do have to leave the system for any reason, your mined and salvaged goods will still count when you return to the system as long as they haven't left your cargo hold.
As for the rest, I typically bring mining lasers with my core rig to opportunistically mine anything decent that I happen upon while looking for cores. Although I haven't seen any subsurface deposits I would deem worth mining, I will keep your suggestion in mind if I do start running into some.
Any idea as to what the top merit-makers are doing? I'm thinking they have to be filling their FCs with something and dumping it all at once at new week opening for the shock & awe factor.
They'd be laser mining platinum in a power-owned system where the station is buying for a high price.
Need metallic rings, owned by power, AND paying 250k or so for plat with high demand.