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So, answering the question, 4 QRUs + 1 comp seems more profitable.
http://thiswarofmine.gamepedia.com/Item_Values
It shows the values of all items compared to eachother.
all of them are value 1 -.-
"Disclaimer: This is an estimate done by selling 1 item at a time to the Trader (Franko) who comes at your door, so it may be undervaluing some of the low value items. E.g. Cigarette's value is probably closer to 1.75 components. Cigarettes are valued at 4x Roll-Up, and 2x the Quality Roll-Up. "
I find the same with bandages and herbal meds - which is best to make once you have the herbs. Bandages have higher value, but by that stage I'm always short of components (fliters, filters, filters...).
First: go to the trader that will give you the most value for cigs i.e. Military Outpost and bring an equal amount of each type of roll-up cigs. Then trade and see which gives you more items in trade. You can trade for one specific item to make it simple to figure out. Example trade one RU or QRU cig for water. Obvously you have to factor in the cost of production. Its not exact but it gives you a ball park estimate. You can do this with Franko too.
Also, moonshine is more valueable than pure alcohol and its more costly to make. I tested this at the Military Outpost but not with Franko or any other trader.