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Did you know some of the old CD games have serial numbers you can enter in to Steam as an Activation Key to get the Steam copy too? for real. It's how I got my Doom3 (OG) and other.
When I mount a CD or ISO it usually ends up in a path like this:
I tried but it doesn't work for me, probably because AvP2 is not avaliable on Steam.
Yes, that path exists and i can open it.
Then create a unique prefix for the game with your preferred wine manager, or even proton manually (for example, for simplicity's sake of showing it schematically, I'll use Proton as per its default path):
Important The above code will create a 32-bit prefix for this game, while in modern systems a 64-bit environment should not pose a problem, if you DO encounter a problem, you can force the prefix to be 32-bits. In my experience wine gracefully handles win32 applications. Alas some distributions can require this, I trust it is not an issue on the Deck, though. Still I add this for completeness sake, if anyone extrapolates to other Linux systems.
Assuming the game image is mounted in /run/media/deck/ all there is to it now is:
Once the setup has finished, you should install the latest patch (which apparently adds a no-cd patch to the game), or grab a no-cd patch and substitute accordingly. I should mention that you should be able to navigate to the prefix just like any other directory on your drive, or like Proton prefixes. Once installed, you can create a little script to launch the game and add that to Steam as a non-steam game or add the executable directly as a non-steam game (some folks have been able to install programs in this fashion, directly from gaming mode, but I cannot comment on that). I do know that you can add some games installed in this fashion and Proton will figure out the prefix, though I usually create a launcher script to handle that myself. It is up to you.
Also most Wine managers will perform this on their own just fine, allowing you to even leverage Proton. I wanted to illustrate what is happening behind the scenes, as better understanding of what is involved translates into better being able to handle issues should they present.
Hope this helps, and happy gaming.
Thanks for your effort!