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I found out that TRANSITIONRPM 160 works for both types of fuel, it stresses out a bit more and takes more time with NO2 but works reliable.
Also I am using some logic to automatically empty and restart the centrifuge.
https://imgur.com/a/v7UtGY4
memory: 0, LR(logic reader): centrifuge reagents
LC(logic compare): memory less LR, LW: MU Centrifuge On
MU: LC not
LR: Centrifuge RPM, LC: LR less LC, LW: LC Centrifuge open
the orange wire on top goes to the centrifuge's data, red is only power and wired behind. Other wires are made so that there are only relevant devices selectable (no need to rename the LRs for identification)
It uses the fact that the centrifuge automatically brakes when it is full. It will wait until RPM is 0, then switch it off and open it. As soon as reagents goes down to 0, it will switch on and close it again.
For NO2/H2 a 50%:50% ratio should be ideal, in my setup this achieves over 1000RPM. Try verifying that your fuel is indeed 50:50 mix of NO2 and H2, if your fuel mix is off by more than few percent it may have performance impact.
Alternatively one thing that may also have an effect is fuel mix temperature. I usually have fuel mix around 20C - if you have something much colder it may have an impact (untested)