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Also blowing it off with compressed air outside might help too. I mean it is probably embeded in the dust bunnies.
You would have to replace EVERYTHING NOT METAL. Anything that is porus like plastic and foam and such will never stop smelling like smoke.
Using compressed air will just blow any ash or such into a corner, you need to use a vacuum.
There are things you can do like get an enzyme based air freshener but that will only disguise the scent for a little while and could damage the electronic components in a computer or even cause a fire.
Basically you have to clean and absorb the stink in some way. There are all kinds of tricks for cars (baking soda, activated charcoal, dryer sheets, antibiotic pet shampoo and so on), but I don't know how well it would work with a computer.
Alternately, you could resell it and buy a new(to you) one, but ask if they're a smoker this time.
The problem is the motherboard and fans and such are mostly plastic as well and there is not much you can do there other than take everything apart and try to carefully clean it as best as possible.
There is the smoke smell and then there is the harder to remove tar and nicotine.
If the case is plastic then replacing it would be a good idea, again especially if it has porus (rough) plastics but you would have to replace all the fans as well as they most likely got the brunt of the smoke, likely getting all gunked up in the coils of the fans as well.
All in all for a computer I'd say depending on how annoying it is to you it would be better just to get or build a new computer.
So yeah...if it's really bad, there's not too much recourse. Cleaning the case, changing easy to change wires, new PSU/fans etc...but after a while, you may as well just get a new rig instead of doing all of that, if it's still bothering you a lot.
That said, like any musty piece of furniture, or like those foam mattress pads that stink to high heaven when you first unroll them, if you just ventilate the room well for the first several days, it's highly unlikely it'll make your whole house or room smell like an ashtray on any permanent basis. It's not the same as actually smoking yourself.
I'd be more concerned about parts longevity. In the old old days, when PC's were a little less "delicate" and didn't run as hot, they could still last a really long time even when coated with cig. tar. But these days ... it's more unpredictable/less likely, imo.