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https://i.imgur.com/m7ffqhP.png
Also, just realized that while you say buying is the issue in your opening post, the title suggests downloading is the issue.
This should be the functional page: http://store.steampowered.com/app/12120/Grand_Theft_Auto_San_Andreas/
Although, the embedded link's [Add to cart] is more often than not broken, so you should click the banner (the icon) and then [Add to cart] on its Store -page.
No, you can not transfer funds from one account to another.