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Also make sure that your brother has a account too that he at least logged in once on that laptop.
Your brothers account then should appear in your Family Share list in the client.
Mark his account as authorized and then you can permanently log out of the account and your brother can switch to his account.
All the games that can be shared will appear in his library on the laptop.
You could get him his own Steam account, and use Family Sharing the games to his account. Then, he'd be playing as himself, though there are some odd things that happen to shared games, starting with how you can't play any of your games if he's playing any other games in your library, and then other oddities involving DLC other aspects.
https://support.steampowered.com/kb_article.php?s=326fddb7cd1076d7fc0783951caabfe8&ref=3784-QLBM-5731
Alternatively, you could let him use your account but put a Family View restriction on it. It's basically a way for you to choose what games and other features are restricted on the account, until you put in a Family View password. For example, you could set it so that he can't use chat or make purchases or even play certain games.
You'd still not be able to play your own games if he's playing them, but you also don't need to make a separate account.
https://support.steampowered.com/kb_article.php?ref=5149-EOPC-9918
I've done the latter before, and you can easily check out the features yourself.
For example, you can choose to restrict the following:
I'd just restrict all of them, by not selecting any of them to allow.