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Or tie your card to PayPal, and purchase through PayPal. Problem solved.
When people talk about using debit cards on steam, they're talking about cards that are technically visa/mastercards which directly debit their account instead of extending a line of credit.
Your RBC card is not one of those. You cannot use it on steam. Use paypal/pre-paid steam wallet codes.
As Daggoth says above, when people talk of debit cards on stema they are bank=backed or VISA appointed or similar. In other words, it will have the logos EMBLAZONED front and centre on the card. If it ain't there, you can't use it.
Your only course of actions left are to first check to see if you can use it on Paypal, or try to find a manual pre-paid debit card you can use instead.