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Sterling silver is slightly lighter in colour and it has a material value a bit lower than silver (8 instead of 10) but equal to the 3 silver and 1 copper needed to make it.
It is not very useful unless a dwarf really likes the material in particular or if you want to make a bit more valuable things out of your silver by throwing some copper into it.
As for your coin minting, if the task says it needs a specific material (like sterling silver) than it needs that exact material and not some other form of it (i.e. if you want to mint bronze coins you need bronze bars not black bronze bars nor bismuth bronze bars, but bronze bars).
Here's the full list of all metals currently in the game and what they are made of:
https://dwarffortresswiki.org/index.php/Metal