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Also, you can try launching the game directly through \Steam\steamapps\common\Sid Meier's Civilization V - CivilizationV_DX11 (Sadly, no DX9 option exists in this manner, as far as I know).
If you are unsure, then are you playing on a Windows XP operation system?
As for the issue of it not running, have you performed the first time setup, as mentioned?
After accepting this pop-up, you will get a small Steam window with the text "performing first time setup". This first time setup will usually contain 2 or 3 steps, and the window will tell you what step you are on. One of these steps usually includes installing DirectX (this does not cause any harm at all if you already have DirectX installed).
If you aren't promted with the pop-up when starting Civilization V, try running the "Launcher.exe" file located in the same folder as stated above.
Make sure to run it as an administrator.
Also, if I am not entierly wrong, there is supposed to be a file located in the Civilization V folder or in a subfolder that contains data on wheter or not the First Time Setup should be performed or not, as to avoid the First Time Setup to be initialized on every startup.
This is atleast the case with other Steam games, where you get promted to perform the First Time Setup on each startup, and in order to fix this bug, you have to edit said file.
Finally, a friend of mine had a similar problem with the windows prompts did not show up (this was on a Windows 7 machine). He managed to fix this problem by restarting his computer. You could try restarting your computer and immediately run the Launcher file as an Administrator, if all else fails. However, I cannot at all confirm that this will make the game work.