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Ok, let say Snake Eyes is not there (assuming that you have killed her before defeating Genichiro), after arriving at the Poison Pool Idol, you grapple up. Now use the green balloon which increases the drop rate of rare items. But you will have to have the Daemon Bell as well. This will further increase the drop rate of rare items. However, the drop rate will only be around 1 in 30 or even as high as 1 in 50 to 60 (I don't have the exact figure but from my personal experience, if you don't have the Kuro's Charm, the drop rate will definite be around 1 in 30). These canon dudes do drop the fulminated mercury but with the drop rate in mind, you really have to have quite a few of those green balloon, at least 10. However, this will only allow to farm just enough to upgrade ONE prosthetic tool, i.e. about 3 to 4 mercury.
You can pop a green sugar to go invisible if you are worried about being spotted. But from my experience, if you time it right, you won't get spotted.
Saying all these, there are two ways to farm. One is to go around and kills ALL 3 canon guys. Always do it in this order, the one nearest to the Poison Pool Idol first, then the one at the far end of the area, and the one at the centre area the last. Then hop back to the idol to rest. Repeat. You should be able to do at least 3 round before the effect of the green balloon runs out. Oh, never use the personal idol as this will cancel out any effect left of the green balloon. Always hop back to the Poison Pool Idol and rest there.
The 2nd way is to just killing the canon guy nearest to the Poison Pool Idol. Then hop back to the idol to rest. You should be able to kill him 5 to 6 times before the effect of the green balloon runs out.
Both Destro and Snazzy Dragon are correct. The area they mentioned will drop mercury but this is the final stage of the game. But it will be much harder as you will have the Daemon Bell plus without the Kuro's Charm especially fighting the Red coat samurai with twin blades. Destro's method is the safest.
Hope this help. Good luck and have fun. :)