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A counterpoint to that though is that fertilzer is already something that you end up with way way more than you need and it does not dissipate. It also involves eventually needing to do things like feeding substantial amounts of it to an incinerator, which then becomes ash. So ash becoming fertilizer becoming ash is a never ending waste loop I for one do not want to have to deal with.
For everything else you mention, also valid, but there can be a few different issues causing your incinerator output ash to become contaminated. One of the main ones is simply a problem with what waste you are feeding it.
Also, if you have a waste separation facility in line before the incinerator. If any of the separation outputs becomes full and overloaded, some of that waste will get through. For example, if your aggregate storage for construction waste becomes full. The separation facility does not just stop running, it allows the construction waste to flow through the main waste line that is being sent to the incinerator. So you have to be careful with your waste setup, and the logistics of carting away outputs. That includes not only making sure trains coming to gather the outputs are set correctly, but that whatever is happening at their destination is automated to the degree that they never become full. In following the above example, if you bring (or send directly) all your construction waste to a recycling facility turning it into gravel.. you need to make sure that gravel storage never becomes full. (if it does.. you end up feeding mixed waste mixed with construction waste into your incinerator. This can jam up its internal input and it will simply stop working entirely)
In regards to your trucks and the issue of picking up ash/cinder first, well, the ash is classed as mixed waste. That means you would need the truck set to particularly pick up the non mixed waste portion.
Said in completely non negative tone: Nothing you are experiencing is an unsolvable problem requiring micromanagement. There are solutions to making sure this problem simply does not happen in the first place. Take it as a challenge to re-think the fundamentals of your setup so that it requires no micromanagement.
Edit: it is important to note that if your separation facility's internal output, or the incinerator's internal input become contaminated.. you may/will need to utilise waste trucks to empty those buildings of the contaminated waste before you can return to clean output/input. Everything I've said above is due to dealing with what you are dealing with. I wish you luck.
Edit 2: Bottom line, the goal is to ensure the incinerator output is always pure ash, with that ash being brought elsewhere to rail dumps for it to dissipate completely.
Edit 3: Note that in working out your waste management system/kinks, it is almost necessary that you know that you can click 'demolish' on a factory connection as a method of temporarily turning it off. Then when whatever problem has been fixed, you simply cancel the demolition. For factory connections, treat demolition as an off/pause switch.
Also I guess your game is heavyly modded cause composter doesn't produce any ash, organic is straight turned into fertilizer and that's all.