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Most of the solid waste should come from the iron ore processing plant, in the form of iron ore tailings.
The ratio of steel per iron could also be skewed due to manufacturing losses, as we are getting finished structural steel, not pig iron. Mill scale, pickling, scrap from forming processes, losses from refinement of pig iron into steel (especially if puddling is used), and other loses could reduce the output further.
Most of the pollution from the steel industry though comes from the coking ovens.