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Base chance of ability is 20%, I think.
So with that gear: 0.2×(1+131.28) = 2645.6%
Then you can get three feats (20, 40 & 80%) and the 50% boost from Vow of Harmony, all are multiplicative. So 26.456×1.2×1.4×1.8×1.5 = 120 max chance at one away (=12000%).
Sadly, I can't go farther for now as the ability is temporary disabled until they fix it. I can't compare to my gear value nor figure the curve of the skill and its formula.
Not even remotely impressive, all things considered (and the 160k total ilvls it takes to get there). And his effective trigger chance does not appear to go above 100%, so he can't multi-skip either.
[Ability chance]/[current missing objective]^2
Capped at 100% of course
So the answer is, at item cap and with 7+ vow of harmony stacks:
120/25^2 = 120/625 = 19.2%
And for a more in depth exploration:
At 25: 120/25^2 = 120/625 = 19.2%, so 19.2% chance to have proc
At 24: 120/24^2 = 120/576 = 20.83%, so 36.03% chance to have proc
At 23: 120/23^2 = 120/529 = 22.68%, so 50.54% chance to have proc
At 22: 120/22^2 = 120/484 = 24.79%, so 62.81% chance to have proc
At 21: 120/21^2 = 120/441 = 27.21%, so 72.92% chance to have proc
At 20: 120/20^2 = 120/400 = 30%, so 81.04% chance to have proc
At 19: 120/19^2 = 120/361 = 33.24%, so 87.34% chance to have proc
At 18: 120/18^2 = 120/324 = 37.04%, so 92.03% chance to have proc
At 17: 120/17^2 = 120/289 = 41.52%, so 95.34% chance to have proc
At 16: 120/16^2 = 120/256 = 46.88%, so 97.52% chance to have proc
At 15: 120/15^2 = 120/225 = 53.33%, so 98.85% chance to have proc
At 14: 120/14^2 = 120/196 = 61.22%, so 99.55% chance to have proc
At 13: 120/13^2 = 120/169 = 71.01%, so 99.87% chance to have proc
At 12: 120/12^2 = 120/144 = 83.33%, so 99.98% chance to have proc
At 11: 120/11^2 = 120/121 = 99.17%, so 99.9998% chance to have proc
At 10: 120/10^2 = 120/100 > 100%, so 100% chance to have proc
Things are better with Sentry, as it starts at 17, so 41.52% and reach the cap at 10 quest items required too. Cumulative chances are with Sentry: 17: 41.52% / 16: 68.93% / 15: 85.50% / 14: 94.38% / 13: 98.37% / 12: 99.73% / 11: 99.998%
But clearly not very impressive anyway for the huge investment, but the good point is it will be a killer buffer probably at that amount of gear in a good (neutral) party, due to emerald grove buff (and probably AA with potential Ceremorphosis +3).
It was intentional, since "you can't get both Minthara and Halsin in your party at the same time in BG3". That said, Halsin's numbers are worse in almost every regard.
On an unrelated note, you can field both Halsin and Minthara at the same time here, similarly using a bug/exploit, which is pretty ironic.