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normal ammo will always be better for piercing because yeah incendiary and poison can't hit through anything.
As far as i'm aware incendiary and bleed ammo will increase in intensity/speed the more bullets you land, i would assume poisons effect lasts longer with more shots as well. Though its very rare you need more than 2 or 3 shots anyways.
but yeah it works similiar to dum dum and incendiary just to stop people from topping up so you can get that pistol swap kill or maybe a second shot without them being able to heal.
I personally like to bring incendiary on one spark ammo slot to deal with all pve and to one tap barrels.
All the poison ammo does is apply the poison effect, which distords the player's vision and hearing and prevents them from healing/regenersting health for the duration of the effect.
No damage over time and no extra damage either.