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Great Luck: 3pc MR Kirin armour
Good Luck: 2pc Guildworks and(?)/or Guild Palace armour
When hosting Kushala slaying investigation, had to kill it 3 times to get one shadowcore ore and that was with the Kirin set bonus great luck.
and to clarify something : they can ONLY drop from ELDER DRAGON tempered investigations. not t3 in generel. rajang/pickle/bagel all count as t3 tempered but they will give you phantomcore ores not shadowcore. the monster has to an elder dragon to get some of em in the first place. so no easy bagel farming for it unlike the decos where bagel is pretty much the best target from them all (excludeing vaal maybe)
Not rare, not at all. If you're specifically looking for that one single piece to upgrade your best buddy charm or whatever it's incredibly annoying though...but simply playing the game will end up with you having a large stock handy etc.
Certainly this was the "last" material to get for me. Everything else I had sooner.
You do have to wait until you are MR 100 to get Shadowcore ore, true enough, which definitely adds to its rarity, but considering fighting Tempered Elder Dragons is what you've been working towards at that point I'd imagine as soon as you hit MR 100 you'd be doing them in your Guiding Lands and immediately farming their Investigations for decorations, etc.
Meh.
You'll be hungry for a lot of things in the end game. There's so many things you need, it's pretty overwhelming, but at least Phantomcore and Shadowcore Ore are universal among many items, not like needing a specific Tempered Elder Dragon material in the Guiding Lands or something.
Then you're quite lucky, or i was unlucky, back when i needed one i took me 5 hunts to get one.