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+10 can become chaos
+15 is different path- entirely physical
P.S. Dark Souls Wiki is your friend. Refer to Jade Fist's link or this one[darksouls.wikia.com] for details
ftfy
+10 fire and +5 chaos are somewhat similar high-tier fire upgrade, chaos is best but requires 10 humanity in counter (for full dmg), fire +10 is slightly less good but you don't have to worry about the scaling
OP: +15 is the best dmg output if you have high stats (dex/str). Chaos is a downgrade then.
Here a link for more info: http://darksouls.wikidot.com/titanite-and-scale-farming