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I've been playing Dark Souls since the game was released for PC. After I got good, I played almost everyday for 1-2 hours a day, because I was working on speedruns. For my runs, I use normal enhancement, so I get all the large and very large embers, use the normal titanite, etc. I don't like to use BK weapons like all the "pros" do. So, for my runs I end up killing at least a few Dark Wraiths for spare chunks, so I've had hundreds of opportunities to get a Slab.
Anyway, I have accumulated about 1,400 hours on Dark Souls while experimenting with speed runs. Then, last week, I decided to just do a casual run and I was tooling around in Londo with zero humanity, and no item find ring. First Dark Wraith I kill drops a slab. I literally have never seen that before and I was so stunned that the next Dark Wraith killed me after I picked it up.
So, the drop rate is 1 slab, every 1,400 hours.
You're welcome.
Enemy drops:
Dropped by the Prowling Magus & Congregation boss in Brightstone Cove Tseldora.
Dropped by the Crystal Lizard in front of the bridge leading to Drangleic Castle.
Dropped by Stone Soldiers in Drangleic Castle.
Dropped by Stone Knights in King's Passage.
Dropped by two Crystal Lizards in Dragon Aerie. One near the first dragon (first Lizard in the open area), another one near the third (on a platform).
Dropped by the Imperfect's in Dragon's Sanctum.
Dropped by the Afflicted Graverobber, Ancient Soldier Varg, Cerah the Old Explorer boss in Cave of the Dead.
Dropped by Iron Warriors.
Dropped by Bell Keeper Covenant Phantoms
Chest and Corpse locations:
Underneath the room in Forest of Fallen Giants where you get ambushed by multiple Ballistae. Use a Pharros' Lockstone to find a secret wall with a Slab inside a chest.
Inside a wooden chest in the acid pool in Drangleic Castle. Bonfire Intensity 2+ only.
In Dragon's Sanctum, inside a chest in the room with the first two Sanctum Knights.
Behind some boxes near the Life Ring +3 chest in Brume Tower.
one in a chest in Eleum Loyce, the room with the many chests that have to be unfrozen by alsanna
Other sources:
One is received as a reward for reaching Rank 1 in the Bell Keeper covenant.
One is given to you by Steady Hand McDuff after spending 14,000 souls on his services (must be services like reinforcement or repair, not items in his stock). You can also kill him for the Slab.
Possible to receive when trading Small Smooth & Silky Stones, Smooth & Silky Stones or a Petrified Somethings with Dyna and Tillo in Things Betwixt.
source: http://darksouls2.wikidot.com/titanite-slab
Lol. I love how common they are in Dark Souls 2. it feels good that it's so easy to fully upgrade so many regular weapons. The best part is that you get a titanite slab from a metal chest in the intended first area of the game, the Forest of the Fallen Giants (you need a pharaoh's lockstone to access it but that's easy to get and if you start as the explorer class you start with a pharaoh's lockstone in your inventory).
Edit: the stone soldiers (those are the ones you encounter after the first Drangleic castle bonfre) supposedly have high lightning, fire, and magic resist but I don't recall ever having trouble with all of those damage types. They and the stone knights are weak to dark damage though.
http://darksouls.wikia.com/wiki/Coal_Tar
Also Chloanne will sell unlimited titanite chunks after you beat Nashandra.