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I did create biomass repeatedly days ago on Beta like this: Shred potatoes. Toss that reagent mix from the recycler into the electric centrifuge. So ... I don't know what to tell you.
Wait, you can shred a cooked potato,
and that will give you a potato after the centrifuge? Is it edible, can it be cooked?
Or maybe that's just a leftover from way back when centrifuge didn't remove gases.
The gas neither released nor deleted. It's contained in the biomass itself. You need to further process it to release the volatiles.
Easiest way to do that is by turning the biomass into charcoil, e.g. "roasting" the biomass (ideally, using an arc furnace).
Keep in mind that the arc furnace creates enough heat to make those volatiles instantly react with any oxygen that might be around. To safely capture volatiles from biomass, make sure the arc furnace is place in small vacuum chamber, or a room filled with innert gas. Otherwise, the volatiles released will instantly ignite, and aside from losing valuable gas, it's not hard to kill yourself. Vacuum works better, because you will want to suck out the atmosphere once the roasting process is done, to capture the volatiles anyway. Aside from volatiles, roasting biomass also produces some pollutant, so be ready to separate them either via atmospherics kit, or use the condesation trick.
This is the only way of producing volatiles (and consequently, water) on ice-less planet runs. The amount of volatiles you can produce from biomass this way is pretty wild.
An alternative way of getting volatiles from biomass is via composter. Both types of composters actually release volatiles much like when you roast the biomass in a furnace. HOWEVER, composters do consume water, which makes it a hydrogen net loss process as far as I can tell - if you are making volatiles to supply yourself with water, the amount a composter will consume will be greater than the amount you could generate via H2O combustion.
Anyway, much like when making charcoil, keep in mind the easy ignition, and make sure your composters are in an atmosphere where either no oxygen is present, or at least there are no things that could spark it.
Composter seems to work, it releases more volatiles that what's contained in the water it uses up. But It's hard to tell how much exactly.