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think you got this backwards....
what I normally do is match the earths atmosphere at 78% N2, 20% O2, and and because we do not have argon, helium, etc.. I just spend the last 2% on CO2 for plants... works out Great.
https://climate.nasa.gov/news/2915/the-atmosphere-getting-a-handle-on-carbon-dioxide/#:~:text=By%20volume%2C%20the%20dry%20air,methane%2C%20nitrous%20oxide%20and%20ozone.
Yea that will for sure kill you in atmo. In your tank it will likely kill you too. Over 30% nitrogen is toxic in the game.
Currently the canister in your suit should be 100% oxygen. I'm not sure if that is going to change with coming changes, we will see.
are you confusing Nitrous oxide(No2) with Nitrogen(N2)?
No, N2 accounts for about 78% of Earth's atmosphere. The NO2 content is thankfully negligable, because NO2 is toxic.
Your idea was good, but you forgot that your space suit is a closed system. Using an air mix containing other gasses besides O2 will lead to those gasses accumulating if not filtered out.
For example: 100 kpa with 21% Oxygen makes a ppO2 of 21 kPa ... this "O2" pressure is needed for your body so it can absorb enough Oxygen. If you lower the pressure to 20 kPa then you need 100% Oxygen to reach a ppO2 of 20kPa ...
The reason you'll die with N₂ in your suit mix and no N filter is, your breathing doesn't consume it and it's never removed from your helmet, so when your breathing does consume O₂ and convert it to CO₂, which does get filtered out, the 80% volume of N₂ stays right where it is, in your helmet, and the 20% volume of O₂ which you used gets replaced ... from your suit canister, with an 80/20 mix. Leaving you after a few breaths with an 80% + (80%*20%=16%) 96% N₂, 4% O₂ mix in your helmet, and it only gets worse from there.